Ngo-1904, usosayensi waseBrithani u-FS KippiHg wahlanganisa ngempumelelo inhlanganisela equkethe i-silicon-i-carbon bond - i-dimethyldichlorosilane - isebenzisa i-Greiner's reagent ne-silicon tetrachloride, ngaleyo ndlela wabeka isisekelo socwaningo lwe-organosilicon: 2CH₂MgCl+SiCl→(CH₃)₂SiCl₂+2MgCl₂
Akukhona nje kuphela ukuthi kunezinhlanganisela eziningi ze-organosilicon ezilula i-R-Si-X ezihlanganisiwe, kodwa futhi nama-polysiloxanes angama-cyclic kanye ne-linear (izinto ezinamabhondi -}e-Si{3}}O{4}}Si - njengohlaka) avele. Ukwengeza, phakathi nokuhlolwa, kutholwe ukuthi lapho i-alkyl{7}}ingxenye yama-silane eshintshwayo aqukethe amaqembu asebenzayo e-hydrolyzable etholwa, izici zamakhemikhali ze-dimethyldichlorosilane zazisebenza kakhulu. Ngemuva kwe-hydrolysis, ingakhiqiza ama-silanol. Ngokufingqa phakathi kwe-silanediol ne-silantriol molecule, umgomo wokukhiqiza ama-polymer aphezulu ane-silicon{10}}ibhondi ye-oksijeni{10}njengohlaka lungafinyelelwa, okuvula indlela yokuhlanganiswa kwama-silicone resins. Amanye alawa ma-polymer anamafutha, amanye anenhlaka{12}}njenge-resin, kanti amanye afana nejeli{13}}. Lawa amafutha e-silicone ahlukahlukene, ama-silicone resins nama-silicone rubber esinawo namuhla. Kodwa-ke, ngaleso sikhathi, i-polymerization phenomena eyabonwa yayinganakwa futhi ukubaluleka kwe-polymerization kulo mkhakha akuzange kuqashelwe. Ngakho-ke, lawa ma-polymer ahlukaniswa njengokucasulayo{17}}yimikhiqizo.
I-FS KippiHg ibisebenza emkhakheni we-organosilicon chemistry iminyaka engu-45 futhi ishicilele amaphepha ocwaningo angama-54.
I-FS KippiHg yaziwa kabanzi njengomsunguli ovelele we-organosilicon chemistry emhlabeni wonke. Impumelelo yakhe ilele ekuhlonzeni indlela yokuhlanganisa inhlanganisela ye-organosilicon kanye nokuthola inani elikhulu lezinhlanganisela eziqondile ze-organosilicon, abeke isisekelo samakhemikhali e-organosilicon. Kepha lesi akusona isiqalo sekhemikhali ye-organosilicon yanamuhla.
Ngokuphathelene nomsebenzi wetiyori, ukuhlanganiswa kwama-asymmetric silicon athomu athomu sekuqaliwe, okwenza izimo zocwaningo lwama-isomers anezithombe ze-organosilicon.